Safety data sheet according to 29cfr19101200 and ghs rev. Furfural is obtained by the hydrolysis of vegetable matter, such as corn stumps, rice offal, and other materials that contain pentosan. Furfuralwater vaporliquid equilibrium 0 20 40 60 80 100 120 140 160 180 0 10 20 30405060 70 80 90 100 wt % furfural temperature c based on data from mains, g. Furfural vapor is an irritant of the skin, eyes and respiratory tract. Links with this icon indicate that you are leaving the cdc website the centers for disease control and prevention cdc cannot attest to the accuracy of a nonfederal website. The global furfural market demand was 300 kilotons in 20. In this study, the acidcatalyzed conversion of xylose and xylan to furfural by microwaveassisted reaction was.
Destruction by the vapor phase reaction with photochemically produced hydroxyl radicals is expected to be an important process with an estimated halflife of 0. Except where noted, spectra from this collection were measured on dispersive instruments, often in carefully selected solvents, and hence may differ in detail from measurements on ftir instruments or in other chemical environments. Furfural serves as a raw material in the preparation of furan, tetrahydrofuran, and tetrahydrofuryl alcohol and in the manufacture of furan resins, fungicides, and such pharmaceuticals as furacin. Material safety data sheet northwest missouri state.
Furfural is extensively utilized as a solvent during the manufacture of refractory materials, resinbonded grinding wheels, and butadiene extraction due to its superior physical properties. The global furfural derivatives market is anticipated to expand at a significant pace. Product and company identification product name 2furaldehyde cat no. Furfural derivatives are tested as automotive fuel in blends with gasoline. Sds of 5methyl furfural, safety data sheets, cas 620020. The production of furfural via diluteacid hydrolysis of lignocellulosic materials has been under study for many years. Furfural is a biomass derivedchemical that can be used to replace petrochemicals. Ac18100, ac18110, ac18125, ac181100250, ac181102500 synonyms furfural. Buy 5chloromethylfurfural cas 1623887, a biofuel precursor used to co process oil crops into biodiesel, from santa cruz. Furfural yield calculations are simple in batch systems. Background furfural cas no 98011 and ec no 2026277 has a widespread use in cosmetic products as a perfumery ingredient. Safety data sheet ifc, supplier in furfural and furfuryl. Furfuryl alcohol sds, msds sheet, suppliers and manufacturers represantative.
Sampling and analytical methods furfural organic method. Expansion of the market is attributed to the increase the demand for furfural from plastics industries and refineries. Analysis of process parameters during simultaneous furfural stripping. There was a very high recovery more than 90% of dose of radioactivity in all dose groups in 72 hr.
In the atmosphere, furfural is expected to exist predominately in the vapor phase. Furfural c 4 h 3 ocho, also called 2furaldehyde, best known member of the furan family and the source of the other technically important furans. Furfiural yield values have been reported to be 4040% of the theoretical value in closed systems and 5080s when furfural is rapidly removed from the reaction medium. The chemistry and technology of furfural and its many by. Furfuryl alcohol, food and flavor ingredient, flavis no. Longterm exposure to furfural may cause sensitization of the skin, loss of the sense of taste, numbness of the tongue, and breathing problems. Document can be downloaded from legislative information. View download disclaimer the sds samples above are collected from the internet by chemblink and displayed here for the tutorial purpose only. Furfural appears as colorless or reddishbrown mobile liquids with a penetrating odor. Furfuraldehyde cas no 98011 material safety data sheet. Hazards identification target organs eyes, respiratory system, skin, liver, kidney, spleen potential health effects. Furfural is an organic compound with the formula c 4 h 3 ocho. Du pont starts the production of adiponitrile for the manufacture of nylon 6.
It is a product of the dehydration of sugars, as occur in a variety of agricultural byproducts, including corncobs, oat, wheat bran, and sawdust. As in any fire, wear a selfcontained breathing apparatus in pressuredemand, mshaniosh approved or equivalent, and full protective gear. Hazards identification see toxicological information section 11 medical conditions aggravated by overexposure preexisting disorders involving any target organs mentioned in this msds as being at risk may be aggravated by overexposure to this product overexposure signssymptoms ingestion. Buy high purity furfural analytical standards from chem service inc. Download msds of furfural us international furan chemicals bv. Furfural or furfuryl alcohol msds sheet of manufacturers. Finoric, etymologically derived from our business line of fine inorganic, organic and industrial chemicals, is the internationally preferred source for chemicals. Furfural is a liquid chemical produced from biomass.
Du pont abandons the furfural thfadiponitrile process. Material safety data sheet section 1 furfural 1 chemical product and company identification msds name. Several drops of furfural in standard eye tests with rabbits cause significant irrita tion but no irreversible. Dec 17, 2019 furfural countable and uncountable, plural furfurals organic chemistry a heterocyclic aldehyde derivative of furan. The n 2stripping tests were carried out in a 2 l reactor autoclave engineers, with controlled electricheating and stirred at 500 rpm see scheme 1. The fate of furfural 2furancarboxaldehyde was investigated in male and female fischer 344 f344 rats given single oral doses of 1, 10 and 60 mgkg and male and female cd1 mice given 1, 20 and 200 mgkg carbonyl14c furfural. Hazards identification see toxicological information section 11 medical conditions aggravated by overexposure preexisting disorders involving any target organs mentioned in this msds as being at. Iec 61198, mineral insulating oils methods for the determination of 2furfural and related compounds iec 61619, insulating liquids contamination by polychlorinated biphenyls pcbs method of determination by capillary column gas chromatography iec 61620, insulating liquids determination of the dielectric dissipation factor by. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. Atmospheric removal by wet deposition may be a significant.
Furfural article about furfural by the free dictionary. Opinion of the scientific panel on food additives, flavourings, processing aids and materials in contact with food afc on a request from the commission related to furfural and furfural diethylacetal. It has a role as a maillard reaction product and a metabolite. An exothermic resinification of almost explosive violence can occur upon contact with strong mineral acids or alkalis. Items available from stock in japan will be delivered in 12 weeks. Show this safety data sheet to the doctor in attendance. Due to the polar nature of furfural, it will dissolve quite readily and form solutions with a variety of polar organic solvents like methanol, ethanol, chloroform, and dimethyl sulfoxide dmso. Your new online msds binder is a place for you to store the material safety data sheets you need to deploy. It forms condensation products with many types of compounds.
Based on directive 200158ec of the commission of the european communities. Colourless to yellow oily liquid which browns on storage, pungent, sweet, breadlike, caramellic, cinnamonalmondlike flavour, odour resembles benzaldehyde food and agriculture organization. Physical properties of furfural ifc, supplier in furfural. This may be a conservative value due to the lack of relevant acute toxicity data for workers exposed to concentrations above 16 ppm. Material safety data sheet ifc, supplier in furfural and. Furfuralwater solutiontemperature diagram vaporliquid composition vaporliquid equilibrium physical properties of furfural. Find 5 hydroxymethylfurfural flavis no and more foodgrade flavor ingredients at. The revised idlh for furfural is 100 ppm based on acute inhalation toxicity data in humans apol and lucas 1975. Eye contact rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Cdc niosh pocket guide to chemical hazards furfural. Purchase the chemistry and technology of furfural and its many byproducts, volume 1st edition.
It forms condensation products with many types of compounds, including phenol, amines and urea. Use pattern and formulations furfural is a new pesticidal active ingredient intended for use as a fumigant to control root infesting plant parasitic nematodes and fungal plant diseases in greenhouse soil used for growing ornamentals and other nonfood commodities. A list of the physicochemical properties of furfural is provided in table 1. Furfural 98011 buy and find out price and availability, msds, properties of tcis high quality specialty chemicals. Furfural cas 98011 gr for analysis acs find msds or sds, a coa, data sheets and more information. Du pont abandons the furfuralthfadiponitrile process. Download our material safety data sheets for furfural. The strong shift towards the development of biobased chemicals on account of volatile petrochemical prices and growing environmental concerns is expected to remain a key driver for the growth of global furfural market.
Furfural was found to penetrate the skin of rabbits, but with no fatal effect up to 500 mgkg. International furan chemicalsifc is supplier in furfural. Use explosionproof electricalventilatinglightingequipment. Furfural is metabolized rapidly and excreted in the urine as furoylglycine, with a smaller portion 0. Packaging 1 kg in poly bottle 100 g in poly bottle 1, 25 g in glass bottle other notes download our flavors and fragrances catalog to view our entire product line. The information provided on this msds is correct to the best of our knowledge, information and belief at the date of its publication. Furfural appears as colorless or reddishbrown mobile liquids with. Firstaid measures general advice if symptoms persist, call a physician.
It is a colorless liquid, although commercial samples are often brown. Furfural is available commercially at a purity 98% aldrich chemical co. Several drops of furfural in standard eye tests with rabbits cause significant irrita. Furfural is an aldehyde that is furan with the hydrogen at position 2 substituted by a formyl group. Find msds or sds, a coa, data sheets and more information. Subscribe to our newsletter to keep up to date on our latest flavors and fragrances offerings. More information on the manner in which spectra in this collection were collected can be found here. Linking to a nonfederal website does not constitute an endorsement by cdc or any of its employees of the sponsors or the information and products presented on the website. Disclaimer the sds samples above are collected from the internet by chemblink and displayed here for the tutorial purpose only. Korenman and resnik 1930 and animals deichmann and gerarde 1969. Future feedstock for fuels and chemicals furfural, a sister chemical to the increasingly popular hydroxymethylfurfural or hmf molecule, is regaining attention as a biobased alternative for the production of everything from antacids and fertilizers to plastics and paints. It has an aldehyde group attached to the 2position of furan.
Please note that we cannot offer bulk quantities for some products. This website offers all the customers the much needed information on furfural from the technical data sheets, msds, trading information, to the fullfledged information on everything through blogs. Furfural and its derivatives have several possible applications such as pesticides, solvents for separation of. The first scientific opinion sccnfp082204 on furfural was adopted by the sccnfp during. Furfural analytical standards 98011, n121021g chem. In a typical semicontinuous sc experiment operating at 180 c and 10 bar, the reactor was loaded with the corresponding amount of catalyst and substrate xylose, glucose or corncob and heated up to 180 c with deionized water 1.
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